On?surface synthesis of porous graphene nanoribbons containing nonplanar [14]annulene pores

نویسندگان

چکیده

The precise introduction of nonplanar pores in the backbone graphene nanoribbon represents a great challenge. Here, we explore synthetic strategy toward preparation porous from predesigned dibromohexabenzotetracene monomer bearing four cove-edges. Successive thermal annealing steps monomers indicate that dehalogenative aryl-aryl homocoupling yields twisted polymer precursor on gold surface and subsequent cyclodehydrogenation leads to defective containing [14]annulene five-membered rings as characterized by scanning tunneling microscopy noncontact atomic force microscopy. Although C–C bonds producing are not achieved with high yield, our results provide new perspectives for on-surface growth nanoribbons.

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ژورنال

عنوان ژورنال: Journal of polymer science

سال: 2022

ISSN: ['1542-9385', '0098-1273']

DOI: https://doi.org/10.1002/pol.20220003